Amid speculations that Angelina Jolie will tie the knot with long-term partner, Brad Pitt, luxe brand Louis Vuitton has released a stunning image of the Salt star as part of their Core-Value Campaign.

The star, who is also a UN Goodwill ambassador, agreed to be captured by renowned photographer Annie Leibowitz for the campaign in Cambodia.

The unique campaign image shows Jolie sitting in a wooden boat in the province of Siem Reap with a vintage Louis Vuitton Monogram Alto Holdall by her side.

Cambodia holds an important place in Jolie's life as this was the place where the shooting of her famous role as Lara Croft took place in 2000. Jolie later returned to the place several times for humanitarian missions to draw awareness of the masses of the dangers of landmines.

In fact, Jolie's first child Maddox was adopted from an orphanage in Cambodia.

A similar campaign was shot last year featuring Ali and Bono in a vast landscape in Africa.The campaign was a reflection of the couple's long relationship with the region - a reflection of their fight against poverty in the region.

In the year 2009, the core value icons were Buzz Aldrin, Jim Lovell, and Sally Ride to commemorate the 40th anniversary of man's conquest of the Moon while in the year before; it was the legendary filmmaker Francis Ford Coppola, and his daughter Sofia.

Check out the spectacular core-value visuals of Louis Vuitton in the slideshow given:

From Versace to Givenchy Top Fashion Advert Campaigns of 2011
Angelina Jolie at the new Louis Vuitton Core Value Campaign. Louis Vuitton/snapshot.
Angelina Jolie and Other Glam Icons at Louis Vuitton Core Value Campaigns.
Buzz Aldrin, Jim Lovell, and Sally Ride at the Louis Vuitton Core Value Campaign. Louis Vuitton/snapshot.
Angelina Jolie and Other Glam Icons at Louis Vuitton Core Value Campaigns.
Legendary filmmaker Francis Ford Coppola, and his daughter Sofia at the Louis Vuitton Core Value Campaign. Louis Vuitton/snapshot.
Brad Pitt Brad Pitt